Scalar quantities have only magnitude — no direction. They obey simple algebraic addition. Examples: mass (kg), temperature (K), speed (m/s), time (s), energy (J).
Vector quantities have both magnitude and direction. They obey the triangle or parallelogram law of addition. Examples: displacement (m), velocity (m/s), force (N), acceleration (m/s²), momentum (kg·m/s).
This distinction is critical: two 5 N forces can produce a resultant anywhere from 0 N to 10 N depending purely on their directions.